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CAS:38465-86-0|1,5-Cyclooctadienebis (methyldiphenylphosphine)iridium (I) Hexafluorophosphate

CAS:38465-86-0|1,5-Cyclooctadienebis (methyldiphenylphosphine)iridium (I) Hexafluorophosphate

Fòmil molekilè: C34H38F6IrP3
Pwa molekilè: 845.79
Pite: 98 pousan
Pake: 5g / 10g / 25g / 50g / pake esansyèl
Transpò: FeDex / DHL / oseyan anbake / kondisyon kliyan

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Pwodwi Entwodiksyon

Non	1,5-Cyclooctadienebis (methyldiphenylphosphine)iridium (I) hexafluorophosphate
Sinonim	(1Z,5Z)-Cycloocta-1,5-dyèn;iridium;methyl(diphenyl)phosphane;hexafluorophosphate
KAS	38465-86-0
MDL No	MFCD00064800
Pwen k ap fonn	224 degre desanm. (Lit.)
pSA	40.77
Boutèy demè	11.55
Aparans	Wouj Crystalline poud
Sansiblite	Lè ak imidite sansib
Solibilite	Soluble nan asetòn. Ensolubl nan dlo
Kondisyon depo	Anba gaz inaktif (azòt oswa Agon) nan 2-8 degre
pous	InChI=1S/2C13H13P.C8H12.F6P.Ir/c21-14(12-8-4-2-5-9-12)13-10-6-3-7-11-13;1-2-4-6-8-7-5-3-1;1-7(2, 3,4,5)6;/h22-11H,1H3;1-2,7-8H,3-6H2;/q;-1;/ b;2-1-,8-7-
InChiKey	MUHONFTSOCMDH-JXNOXZOESA-N

Aplikasyon:

(1,5-Cyclooctadiene)bis (methyldiphenylphosphine)iridium (I) hexafluorhosphate.CAS:38465-86-0) se yon konplèks Iridyòm (I) kasyonik ki itilize kòm yon katalis. (1,5-Cyclooctadiene)bis(methyldiphenylphosphine)iridium(I) hexafluorophosphate yo te anplwaye pou izomzerizasyon alyl etè nan gliserin ak glikoz nan korespondan 1-propenyl etè yo, ak pwotokòl sa a te wè itilize nan lòt aplikasyon pou chimi idrat kabòn.

Referans:

1. Oltvoort, JJ, et al. 1981. Sentèz. 1981: 305-308.

2. Spijker, NM, et al. 1996. Tetrahedron. 52: 5945-5960.

3. Petitou, M., et al. 2001. Chimi Eur. J. 7: 858-873.

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