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CAS:14647-23-5|[1,2-Bis(difenilfosfino)etan]diklornikèl (II)
Fòmil molekilè: C26H24Cl2NiP2
Pwa molekilè: 528.02
Pite: 98 pousan
Pake: 5g / 10g / 25g / 50g / pake esansyèl
Transpò: FeDex / DHL / oseyan anbake / kondisyon kliyan
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Pwodwi Entwodiksyon
Non | [1,2-Bis(difenilfosfino)etan]diklorikèl (II) |
Sinonim | 1,2-Bis-(Diphenylphosphino)EthaneDichloroNickel;1,2-Bis-(Diphenylphosphino)Eth |
CAS | 14647-23-5 |
MDL No | MFCD00013313 |
Pwen bouyi | 514.8ºC nan 760mmHg |
Pwen k ap fonn | 263-265 degre (lit.) |
Flash Point | 281.7ºC |
PSA | 27.18 |
Aparans | Jòn poud mawon, kristal ak/oswa ti moso |
Sansiblite | Moistre sansib |
Solibilite | Kloròfòm, Methanol (Kòm ti kras) |
Presyon vapè | 3.38E-10mmHg nan 25 degre |
Kondisyon depo | Sere nan yon kote ki fre. Kenbe veso a byen fèmen nan yon kote ki sèk ak byen vantile |
Aplikasyon:Dichloro[bis(1,2-difenilfosfino)etan]nikèl (II)(CAS:14647-23-5) se yon reyaktif ki enplike nan Kumada katalis-transfè polikondansasyon, oksidasyon nan ligand fosfin carboranyl, sentèz nikèl-fè dithiolato idr, reyaksyon Ullmann - reyaksyon homocoupling, ko-katalis pou idroformilasyon alkòl pou sentèz katatènwa sant kabòn Wacker. -type intramolecular aerobic oksidatif aminasyon nan alkenes.
Referans:
Bryan E Barton; C Matthew Whaley; Thomas B Rauchfuss; Danielle L Gray. Hydrides dithiolato nikèl-fè ki gen rapò ak sit aktif [NiFe]-idwojenaz la. Journal of American Chemical Society. 2009, 131 (20), 6942-6943.
Yusuke Ueki; Hideto Ito; Ippei Usui; Bernhard Breit. Fòmasyon sant kabòn kwatènè pa idroformilasyon trè rejyoselektif ak kantite katalitik nan yon gwoup dirije revèsib. Chimi: Yon jounal Ewopeyen an. 2011, 17 (31), 8555-8558.
Baj popilè: cas:14647-23-5|[1,2-bis(diphenylphosphino)ethane]dichloronickel(ii), pri, sitasyon, rabè, nan stock, pou vann
