CAS 250220-36-1|(3-Fenil-1H-inden-1-ilidèn)bis(tricyclohexylphosphine)rutheniM(IV) Dichloride

Spesifikasyon CAS 250220-36-1|(3-Fenil-1H-inden-1-ilidèn)bis(tricyclohexylphosphine)rutheniM(IV) Dichloride

Sentèz deCAS 250220-36-1|(3-Fenil-1H-inden-1-ilidèn)bis(tricyclohexylphosphine)rutheniM(IV) Dichloride

Kondisyon

Etap #1: triidrat klori ruthenium(III) Avèk triphenylphosphine Nan methanol pou 4h; Atmosfè inaktif; teknik Schlenk;

Etap #2: 1,1-diphenyl-2-propin-1-ol Avèk idrogenchloride Nan tetrahydrofuran; 1,4-dyoksan pou 0.5h; Atmosfè inaktif; teknik Schlenk;

Etap #3: tricyclohexylphosphine Nan tetrahydrofuran; 1,4-dyoksan; asetòn nan -20 - 20 degre; pou 10.5h; Solvan; Atmosfè inaktif; teknik Schlenk;

Referans

Polyanskii, Kirill B.; Alekseeva, Kseniia A.; Raspertov, Pavel V.; Kumandin, Pavel A.; Nikitina, Eugeniya V.; Gurbanov, Atash V.; Zubkov, Fedor I.

[Beilstein Journal of Organic Chemistry, 2019, vol. 15, p. 769 - 779]

Baj popilè: cas 250220-36-1|(3-fenil-1h-inden-1-ilidèn)bis(tricyclohexylphosphine)ruthenium(iv) dichloride, pri, sitasyon, rabè, nan stock, pou vann